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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/106

Title: Calix(n)arene-quinone interactions: Molecular recognition of 2,6-naphthoquinone by 5,11,17,23,29,35-hexa-tert-butyl- 37,38,39,40,41,42-hexahydroxycalix(6)arene
Authors: Chawala, H M
Srinivas, K
Meena
Keywords: NMR spectral analyses reveal
2,6-naphthoquinone
hexahydroxycalix(6
1,2,5,8-tetrahydroxy-
2,6-naphthoquinone
Issue Date: 1995
Citation: Tetrahedron 51 ( 9 ) 2709-2718
Abstract: UV, IR and NMR spectral analyses reveal that 2,6-naphthoquinone forms a 1:1 host-guest type of complex with 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41, 42-hexahydroxycalix(6)arene while 1,4-naphthoquinone does not do so at low concentrations (1 x 10AM). 1,4-Benzoquinone forms a 2:1 molecular complex with 5,11,17,23-tetra-tertbutyl- 25,26,27,28-tetrahydroxycalix(4)arene and 5,11,17,23,29,35-hexa-tert-butyl-37,38,39, 40,41,42-hexahydroxycalix(6)arene but no complexation has been observed with 5,11,17,23, 29,35,41,47-octa-tert-butyl- 50,51,52,53,54,55,56-octahydroxycalix(8)arene under similar conditions. 9,10-Anthraquinone, 1,2-dihydroxy-9,10-anthraquinone and 1,2,5,8-tetrahydroxy- 9,10-anthraquinone, show no interaction with p-tert-butyl-calix(n)arenes (n = 4, 6, 8). Studies carried out indicate that 2,6-naphthoquinone can be recognised by 1,17,23,29,35 -hexa-tert-butyl-37,38,39,40,41,42- exahydroxycalix(6)arene even when present in a mixture of quinones and other related compounds.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/106
Appears in Collections:Chemistry

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