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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/1184

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dc.contributor.authorElias, Anil J-
dc.contributor.authorMuralidharan, K-
dc.date.accessioned2006-01-19T06:16:53Z-
dc.date.available2006-01-19T06:16:53Z-
dc.date.issued2003-
dc.identifier.citationInorganic Chemistry Communications, 6(5), 584-588en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/1184-
dc.description.abstractThe first examples of uncharged aryl substituted fluorinated hydridophosphazenes, N3P3F4(Ar)H [Ar=C6H5 (1), p-ClC6H4 (2)] were obtained in an unprecedented manner upon fluorination of diaryloctachlorobi(cyclophosphazenes) (N6P6Cl8(Ar)2) [Ar=C6H5, p-ClC6H4] using KF in acetonitrile. The compounds (1) and (2) were stable to air and moisture, and were characterized by spectral and analytical methods. Compound (1) on reaction with FcCH2P(S)(CH2OLi)2 (Fc=Ferrocenyl) gave endo (3) and exo (4) isomers of ansa substituted hydridophosphazenes. The crystal structure of (4) was determined and the structure shows the ansa substitution on the phosphazene ring, trans to the phenyl group with the hydridophosphazene ring puckered to a partial chair configuration.en
dc.format.extent87242 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectHydridophosphazeneen
dc.subjectFluorinateden
dc.subjectAnsaen
dc.subjectFerroceneen
dc.subjectp-Chlorophenylen
dc.subjectFluorophosphazeneen
dc.titleSynthesis and ansa substitution of novel examples of aryl hydrido fluorophosphazenesen
dc.typeArticleen
Appears in Collections:Chemistry

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