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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/1228

Title: First example of bimetallic complex of platinum(II) with a hybrid organotellurium ligand [(4-MeOC6H4Te)CH2CH2OCH2CH2CH2(2-C5H4N)] (L1) containing 20-membered metallomacrocycle ring: synthesis and crystal structure
Authors: Bali, Sumit
Singh, Ajai K
Sharma, Pankaj
Drake, J E
Hursthouse, M B
Light, M E
Keywords: Platinum
Complex
1-(4-Methoxyphenyltelluro)-2-[3-(6 methyl-2 pyridyl)propoxy]-ethane
Hybrid organotellurium ligand
Crystal structure
Synthesis
Issue Date: 2003
Citation: Inorganic Chemistry Communications, 6(11), 1378-1381
Abstract: 1-(4-Methoxyphenyltelluro)-2-[3-(6 methyl-2 pyridyl)propoxy]ethane (L1) and its complexes [MCl2(L1)]2 (M = Pd or Pt) have been synthesized. The single crystal X-ray diffraction of [PtCl2(L1)]2 · 2CHCl3 shows a bimetallic complex of platinum(II) containing a 20-membered metallomacrocycle ring, which remains stable in solution as shown by molecular weight and conductance measurements. The Pt–Te and Pt–N bond lengths are 2.5409(3) and 2.087(5) Å, respectively. The protons of CH2 linked to Te show a deshielding > 1 ppm on the formation of the two complexes.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/1228
Appears in Collections:Chemistry

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