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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/1251

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dc.contributor.authorPooja Kumar-
dc.contributor.authorShankar, Ravi-
dc.date.accessioned2006-01-24T06:56:13Z-
dc.date.available2006-01-24T06:56:13Z-
dc.date.issued2003-
dc.identifier.citationJournal of Organometallic Chemistry, 687(1), 190-196en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/1251-
dc.description.abstractThe reactions between secondary carbosilanes 1–3 and 1-propylbiguanide/1-phenylbiguanide, H6bigR proceed via SiH/NH dehydrocoupling and afford 1,4-bis(silyl)-5-propyl/phenylbiguanides with the general formula (R1R22SiCH2CH2SiMeH)2·H4bigR, [R1=Ph, R2=Me, R=nPr (4), R=Ph (5); R1=Me, R2=Ph, R=nPr (6), R1=R2=Et, R=Ph (7)]. These compounds represent a new family of pentacoordinate silicon derivatives comprising of [Si-N-C-N-C-N] chelate ring and have been characterized by elemental analysis, FAB mass, IR and multinuclear (1H, 13C and 29Si) NMR spectral studies.en
dc.format.extent284969 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectPentacoordinationen
dc.subjectSilylbiguanidesen
dc.subjectSiH/NH dehydrocouplingen
dc.subjectCarbosilanesen
dc.titleNovel pentacoordinate silicon compounds bearing [Si-N-C-N-C-N] chelate ring derived from biguanide ligandsen
dc.typeArticleen
Appears in Collections:Chemistry

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