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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/1809

Title: Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3O19}·4.5H2O
Authors: Asnani, Minakshi
Ramanan, A
Vittal, Jagadese J
Keywords: Hydrothermal synthesis
Vanadium borophosphate
Single crystal X-ray diffraction
Issue Date: 2002
Citation: Inorganic Chemistry Communications, 6(5), 589 - 592p.
Abstract: Hydrothermal reaction of VOPO4·2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]{V3BP3O19}·4.5H2O (VBPO). Crystal data: monoclinic space group, P21/c, Z=4, a=12.0709(7), b=14.2261(8) and c=18.1104(9) Å, β=95.067(1)0°, . Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19] clusters are linked to counter cations and water molecules through a complex hydrogen bonding network.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/1809
Appears in Collections:Chemistry

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