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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/1809

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dc.contributor.authorAsnani, Minakshi-
dc.contributor.authorRamanan, A-
dc.contributor.authorVittal, Jagadese J-
dc.date.accessioned2006-06-27T09:37:21Z-
dc.date.available2006-06-27T09:37:21Z-
dc.date.issued2002-
dc.identifier.citationInorganic Chemistry Communications, 6(5), 589 - 592p.en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/1809-
dc.description.abstractHydrothermal reaction of VOPO4·2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]{V3BP3O19}·4.5H2O (VBPO). Crystal data: monoclinic space group, P21/c, Z=4, a=12.0709(7), b=14.2261(8) and c=18.1104(9) Å, β=95.067(1)0°, . Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19] clusters are linked to counter cations and water molecules through a complex hydrogen bonding network.en
dc.format.extent188638 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectHydrothermal synthesisen
dc.subjectVanadium borophosphateen
dc.subjectSingle crystal X-ray diffractionen
dc.titleHydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3O19}·4.5H2Oen
dc.typeArticleen
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