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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/2278

Title: Synthesis and characterization of complexes of cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) with p-acetamidobenzaldehyde thiosemicarbazone
Authors: Kanagaraj, G
Rao, G N
Keywords: p-acetamidobenzaldehyde thiosemicarbazone
thiacetazone acts
neutral bidentate
hydrazine nirogen
carbothioamide sulphur
brown-coloured nickel(II) complex
monoanionic bidentate ligand
Issue Date: 1993
Citation: Polyhedron, 12(4), 383-387p.
Abstract: Some complexes of p-acetamidobenzaldehyde thiosemicarbazone (thiacetazone) with cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) have been prepared and their magnetic, spectral and thermal data suggest that the thiacetazone acts as a neutral bidentate ligand binding the metal ion through the hydrazine nirogen and the carbothioamide sulphur. A brown-coloured nickel(II) complex, Ni(TA)2, was isolated and found to be diamagnetic and it contains a monoanionic bidentate ligand (thiol form). All the metal complexes of the type M(TAH)2X2 (where X is Cl, Br, NO3 and SCN) are octahedral, while Ni(TA)2 is square planar in structure.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/2278
Appears in Collections:Chemistry

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