EPrints@IIT Delhi : Item 2074/2278

Please use this identifier to cite or link to this item: http://hdl.handle.net/2074/2278

Full metadata record

DC Field	Value	Language
contributor.author	Kanagaraj, G	-
contributor.author	Rao, G N	-
date.accessioned	2006-11-20T09:28:06Z	-
date.available	2006-11-20T09:28:06Z	-
date.issued	1993	-
identifier.citation	Polyhedron, 12(4), 383-387p.	en
identifier.uri	http://eprint.iitd.ac.in/dspace/handle/2074/2278	-
description.abstract	Some complexes of p-acetamidobenzaldehyde thiosemicarbazone (thiacetazone) with cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) have been prepared and their magnetic, spectral and thermal data suggest that the thiacetazone acts as a neutral bidentate ligand binding the metal ion through the hydrazine nirogen and the carbothioamide sulphur. A brown-coloured nickel(II) complex, Ni(TA)2, was isolated and found to be diamagnetic and it contains a monoanionic bidentate ligand (thiol form). All the metal complexes of the type M(TAH)2X2 (where X is Cl, Br, NO3 and SCN) are octahedral, while Ni(TA)2 is square planar in structure.	en
format.extent	165696 bytes	-
format.mimetype	application/pdf	-
language.iso	en	en
subject	p-acetamidobenzaldehyde thiosemicarbazone	en
subject	thiacetazone acts	en
subject	neutral bidentate	en
subject	hydrazine nirogen	en
subject	carbothioamide sulphur	en
subject	brown-coloured nickel(II) complex	en
subject	monoanionic bidentate ligand	en
title	Synthesis and characterization of complexes of cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) with p-acetamidobenzaldehyde thiosemicarbazone	en
type	Article	en
Appears in Collections:	Chemistry

Files in This Item:

File	Description	Size	Format
kanagarasyn93.pdf		161Kb	Adobe PDF	View/Open