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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/2278

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dc.contributor.authorKanagaraj, G-
dc.contributor.authorRao, G N-
dc.identifier.citationPolyhedron, 12(4), 383-387p.en
dc.description.abstractSome complexes of p-acetamidobenzaldehyde thiosemicarbazone (thiacetazone) with cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) have been prepared and their magnetic, spectral and thermal data suggest that the thiacetazone acts as a neutral bidentate ligand binding the metal ion through the hydrazine nirogen and the carbothioamide sulphur. A brown-coloured nickel(II) complex, Ni(TA)2, was isolated and found to be diamagnetic and it contains a monoanionic bidentate ligand (thiol form). All the metal complexes of the type M(TAH)2X2 (where X is Cl, Br, NO3 and SCN) are octahedral, while Ni(TA)2 is square planar in structure.en
dc.format.extent165696 bytes-
dc.subjectp-acetamidobenzaldehyde thiosemicarbazoneen
dc.subjectthiacetazone actsen
dc.subjectneutral bidentateen
dc.subjecthydrazine nirogenen
dc.subjectcarbothioamide sulphuren
dc.subjectbrown-coloured nickel(II) complexen
dc.subjectmonoanionic bidentate liganden
dc.titleSynthesis and characterization of complexes of cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) with p-acetamidobenzaldehyde thiosemicarbazoneen
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