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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/2396

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dc.contributor.authorIshar, M P S-
dc.contributor.authorGandhi, R P-
dc.date.accessioned2007-01-12T08:29:39Z-
dc.date.available2007-01-12T08:29:39Z-
dc.date.issued1993-
dc.identifier.citationTetrahedron, 49(30), 6729-6740p.en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/2396-
dc.description.abstractThermal addition of tropone to allenic esters (RR1C=C=CHCO2Et, Ia, R=R1=H; Ib, R=H, R1=CH3; Ic, R=H, R1=CH3CH2; Id, R=CH3, R1=CH3CH2) furnishes 4+2 cycloadducts as major products, unlike the reported additions of tropone involving a few other allenic systems. The additions display π-facial selectivity resulting in preference for E geometry at the exocyclic double bond in the obtained adducts.en
dc.format.extent284719 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectallenic estersen
dc.subjectE geometryen
dc.subjectexocyclicen
dc.titlePeri-, regio- and stereoselectivities in thermal addition of tropone to allenic estersen
dc.typeArticleen
Appears in Collections:Chemistry

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