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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/2468

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dc.contributor.authorSingh, Ajai K-
dc.contributor.authorPrakash, K M M S-
dc.date.accessioned2007-02-05T03:18:55Z-
dc.date.available2007-02-05T03:18:55Z-
dc.date.issued1992-
dc.identifier.citationPolyhedron,11(10), 1225-1228p.en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/2468-
dc.description.abstract[ArTe(XTSC)2]Cl (XTSC = benzaldehyde/salicylaldehyde thiosemicarbazone) reacts with sodium salts of dithiocarbamates (DTC) and xanthates (XNT) in a 1 : 2 molar ratio resulting in the formation of [ArTe(DTC/XNT)(NaDTC/XNT)]. IR, 1H and 13C NMR spectral data of these tellurium(II) complexes in conjunction with their elemental analyses, molecular weights and conductance in solution suggest that the two ---CSS- groups coordinate in different ways. One is probably in the η2-mode and the other in either asymmetrically chelated or essentially in the η1 mode. They do not exhibit conductance, probably due to strong Na---S association and exist as monomers in solutionen
dc.format.extent138446 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectDithiocarbamatesen
dc.subjectTellurium(II)en
dc.subjectXanthatesen
dc.subjectMolecular weightsen
dc.titleSynthesis of [ArTe(DTC/XNT)(NaDTC/XNT)] (DTC = dithiocarbamate and XNT = xanthate) through ligand substitution reactions of arylbis(thiosemicarbazone)tellurium(II) chlorideen
dc.typeArticleen
Appears in Collections:Chemistry

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