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http://hdl.handle.net/2074/2468
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| DC Field | Value | Language |
|---|
| contributor.author | Singh, Ajai K | - |
| contributor.author | Prakash, K M M S | - |
| date.accessioned | 2007-02-05T03:18:55Z | - |
| date.available | 2007-02-05T03:18:55Z | - |
| date.issued | 1992 | - |
| identifier.citation | Polyhedron,11(10), 1225-1228p. | en |
| identifier.uri | http://eprint.iitd.ac.in/dspace/handle/2074/2468 | - |
| description.abstract | [ArTe(XTSC)2]Cl (XTSC = benzaldehyde/salicylaldehyde thiosemicarbazone) reacts with sodium salts of dithiocarbamates (DTC) and xanthates (XNT) in a 1 : 2 molar ratio resulting in the formation of [ArTe(DTC/XNT)(NaDTC/XNT)]. IR, 1H and 13C NMR spectral data of these tellurium(II) complexes in conjunction with their elemental analyses, molecular weights and conductance in solution suggest that the two ---CSS- groups coordinate in different ways. One is probably in the η2-mode and the other in either asymmetrically chelated or essentially in the η1 mode. They do not exhibit conductance, probably due to strong Na---S association and exist as monomers in solution | en |
| format.extent | 138446 bytes | - |
| format.mimetype | application/pdf | - |
| language.iso | en | en |
| subject | Dithiocarbamates | en |
| subject | Tellurium(II) | en |
| subject | Xanthates | en |
| subject | Molecular weights | en |
| title | Synthesis of [ArTe(DTC/XNT)(NaDTC/XNT)] (DTC = dithiocarbamate and XNT = xanthate) through ligand substitution reactions of arylbis(thiosemicarbazone)tellurium(II) chloride | en |
| type | Article | en |
| Appears in Collections: | Chemistry
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| singhsyn92.pdf | | 135Kb | Adobe PDF | View/Open |
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