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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/624

Title: Synthesis and characterisation of bis(salicylato)diisothiocyanato silicates: First example of hexacoordinate silicate dianions with six membered rings
Authors: Narula, Suraj P
Shankar, Ravi
Meenu
Anand, Rishi D
Keywords: Silicates
Dianionic
Hexacoordinate
Six membered ring
Bis(salicylato)diisothiocyanato
Issue Date: 1999
Citation: Polyhedron, 18(1-2), 2055–2059
Abstract: Synthesis of hexacoordinate dianionic silicates [(C2H4O3) Si(NCS)2]-2 [BH]2 [B=Py(1),3-MePy(2),4-MePy(3)] bearing six membered rings around a silicon atom are reported. The complexes 1–3 are prepared from a reaction between salicylic acid and the appropriate cationic five coordinate silicon(IV) compounds 4–6. All the compounds are characterised by elemental analyses, molar conductance data as well as IR and multinuclei ( H,13C,29 Si) NMR spectra. FAB mass spectra (NBA matrix) of 1–2 have identified respective cations and anions of these complexes.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/624
Appears in Collections:Chemistry

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