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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/665

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dc.contributor.authorSisodia, Om Singh-
dc.contributor.authorSahay, A N-
dc.contributor.authorPandey, D S-
dc.contributor.authorAgarwala, U C-
dc.contributor.authorJha, N K-
dc.contributor.authorSharma, Pankaj-
dc.contributor.authorToscano, A-
dc.contributor.authorCabrera, A-
dc.date.accessioned2005-08-02T06:58:21Z-
dc.date.available2005-08-02T06:58:21Z-
dc.date.issued1998-
dc.identifier.citationJournal of Organometallic Chemistry, 560(1-2), 35–40en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/665-
dc.description.abstract[{Ru(n6-arene)Cl2}2] (n6-arene=benzene, p-cymene or hexamethylbenzene) reacts with EPh3 (E=P, As or Sb) in methanol to give monomeric cationic arene hydrido complexes [Ru(n6-arene)(EPh3)2H]+ in presence of AgBF4 or AgPF6. However, reactions in presence of triphenylphosphine also yield a symmetrically bridged tris (m-methoxy) complex [(PPh3)3Ru(m-OMe)3Ru(PPh3)3]+.The crystal structure of [Ru(n6-C6H6)(PPh3)2H]BF4 has been determined. Crystal data, monolinic system, space group P21:n, a=14.792 (2) A ; b=14.351 (1) A ; c=17.661 (2) A ; b=102.25 (1)° and Z=4. Crystal structure determination reveals the distortion of the Ru(PPh3)2H= unit in the cation [Ru(n6-C6H6)(PPh3)2H]+.en
dc.format.extent233577 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectArene hydrido complexesen
dc.subjectRutheniumen
dc.subjectPhosphineen
dc.subjectArsineen
dc.subjectStibineen
dc.titleSynthesis and characterization of some arene hydrido-complexes [Ru(n6-arene)(EPh3)2H]+ (n6-arene=benzene, p-cymene or hexamethylbenzene; E=P, As or Sb). Crystal structure of [Ru(n6-C6H6)(PPh3)2H]BF4en
dc.typeArticleen
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