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Please use this identifier to cite or link to this item:
http://hdl.handle.net/2074/665
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| DC Field | Value | Language |
|---|
| contributor.author | Sisodia, Om Singh | - |
| contributor.author | Sahay, A N | - |
| contributor.author | Pandey, D S | - |
| contributor.author | Agarwala, U C | - |
| contributor.author | Jha, N K | - |
| contributor.author | Sharma, Pankaj | - |
| contributor.author | Toscano, A | - |
| contributor.author | Cabrera, A | - |
| date.accessioned | 2005-08-02T06:58:21Z | - |
| date.available | 2005-08-02T06:58:21Z | - |
| date.issued | 1998 | - |
| identifier.citation | Journal of Organometallic Chemistry, 560(1-2), 35–40 | en |
| identifier.uri | http://eprint.iitd.ac.in/dspace/handle/2074/665 | - |
| description.abstract | [{Ru(n6-arene)Cl2}2] (n6-arene=benzene, p-cymene or hexamethylbenzene) reacts with EPh3 (E=P, As or Sb) in methanol to
give monomeric cationic arene hydrido complexes [Ru(n6-arene)(EPh3)2H]+ in presence of AgBF4 or AgPF6. However, reactions in presence of triphenylphosphine also yield a symmetrically bridged tris (m-methoxy) complex [(PPh3)3Ru(m-OMe)3Ru(PPh3)3]+.The crystal structure of [Ru(n6-C6H6)(PPh3)2H]BF4 has been determined. Crystal data, monolinic system, space group P21:n,
a=14.792 (2) A ; b=14.351 (1) A ; c=17.661 (2) A ; b=102.25 (1)° and Z=4. Crystal structure determination reveals the
distortion of the Ru(PPh3)2H= unit in the cation [Ru(n6-C6H6)(PPh3)2H]+. | en |
| format.extent | 233577 bytes | - |
| format.mimetype | application/pdf | - |
| language.iso | en | en |
| subject | Arene hydrido complexes | en |
| subject | Ruthenium | en |
| subject | Phosphine | en |
| subject | Arsine | en |
| subject | Stibine | en |
| title | Synthesis and characterization of some arene hydrido-complexes [Ru(n6-arene)(EPh3)2H]+ (n6-arene=benzene, p-cymene or hexamethylbenzene; E=P, As or Sb). Crystal structure of [Ru(n6-C6H6)(PPh3)2H]BF4 | en |
| type | Article | en |
| Appears in Collections: | Chemistry
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| sisodiasyn1998.pdf | | 228Kb | Adobe PDF | View/Open |
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