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| Title: | Influence of 2-aminopyridine on the formation of molybdates under hydrothermal conditions |
| Authors: | Pavani, Katikaneani
Ramanan, Arunachalam |
| Keywords: | Hydrothermal synthesis
N ligands
Molybdenum
Crystal structure |
| Issue Date: | 2005 |
| Citation: | European Journal of Inorganic Chemistry, 2005 (15), 3080–3087 |
| Abstract: | The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first-row transition metal salts in the presence of 2-aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C5N2H7)4Mo8O26 (1), zero-dimensional (C5N2H7)6Mo7O24·3H2O (2), and the first synthesis of Lindgrenite [Cu3Mo2O8(OH)2 (3)] The structures of these materials were established by single-crystal and powder X-ray diffraction techniques. The crystal structures of wolframite-based MnMoO4 (4) and ZnMoO4 (5) were established by powder X-ray diffraction. The role of 2-aminopyridine (2-ampy) in the formation of the different solids under hydrothermal conditions is discussed. |
| URI: | http://eprint.iitd.ac.in/dspace/handle/2074/762 |
| Appears in Collections: | Chemistry
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