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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/762

Title: Influence of 2-aminopyridine on the formation of molybdates under hydrothermal conditions
Authors: Pavani, Katikaneani
Ramanan, Arunachalam
Keywords: Hydrothermal synthesis
N ligands
Molybdenum
Crystal structure
Issue Date: 2005
Citation: European Journal of Inorganic Chemistry, 2005 (15), 3080–3087
Abstract: The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first-row transition metal salts in the presence of 2-aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C5N2H7)4Mo8O26 (1), zero-dimensional (C5N2H7)6Mo7O24·3H2O (2), and the first synthesis of Lindgrenite [Cu3Mo2O8(OH)2 (3)] The structures of these materials were established by single-crystal and powder X-ray diffraction techniques. The crystal structures of wolframite-based MnMoO4 (4) and ZnMoO4 (5) were established by powder X-ray diffraction. The role of 2-aminopyridine (2-ampy) in the formation of the different solids under hydrothermal conditions is discussed.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/762
Appears in Collections:Chemistry

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