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Please use this identifier to cite or link to this item:
http://hdl.handle.net/2074/762
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| DC Field | Value | Language |
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| contributor.author | Pavani, Katikaneani | - |
| contributor.author | Ramanan, Arunachalam | - |
| date.accessioned | 2005-08-13T07:34:05Z | - |
| date.available | 2005-08-13T07:34:05Z | - |
| date.issued | 2005 | - |
| identifier.citation | European Journal of Inorganic Chemistry, 2005 (15), 3080–3087 | en |
| identifier.uri | http://eprint.iitd.ac.in/dspace/handle/2074/762 | - |
| description.abstract | The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first-row transition metal salts in the presence of 2-aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C5N2H7)4Mo8O26 (1), zero-dimensional (C5N2H7)6Mo7O24·3H2O (2), and the first synthesis of Lindgrenite [Cu3Mo2O8(OH)2 (3)] The structures of these materials were established by single-crystal and powder X-ray diffraction techniques. The crystal structures of wolframite-based MnMoO4 (4) and ZnMoO4 (5) were established by powder X-ray diffraction. The role of 2-aminopyridine (2-ampy) in the formation of the different solids under hydrothermal conditions is discussed. | en |
| format.extent | 299902 bytes | - |
| format.mimetype | application/pdf | - |
| language.iso | | en |
| subject | Hydrothermal synthesis | en |
| subject | N ligands | en |
| subject | Molybdenum | en |
| subject | Crystal structure | en |
| title | Influence of 2-aminopyridine on the formation of molybdates under hydrothermal conditions | en |
| type | Article | en |
| Appears in Collections: | Chemistry
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| EJIC2005a.pdf | | 292Kb | Adobe PDF | View/Open |
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