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http://hdl.handle.net/2074/796
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| Title: | Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3] [enH2] {V3BP3O19} .4.5H2O |
| Authors: | Asnani, Minakshi
Ramanan, A
Vittal, Jagadese J |
| Keywords: | Hydrothermal synthesis
Vanadium borophosphate
Single crystal X-ray diffraction |
| Issue Date: | 2003 |
| Citation: | Inorganic Chemistry Communications, 6(5), 589–592 |
| Abstract: | Hydrothermal reaction of VOPO4-2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]V3BP3O19}.4.5H2O (VBPO)Crystal data: monoclinic space group, P21/e Z=4 a=12.0709(7),b=14.226](8)and c=18.1104(9)AB=95.067 (1)A=3097.8(3)A Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19 clusters are linked to counter cations and water molecules through a complex hydrogen bonding network. |
| URI: | http://eprint.iitd.ac.in/dspace/handle/2074/796 |
| Appears in Collections: | Chemistry
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| asnanihyd2003.pdf | | 519Kb | Adobe PDF | View/Open |
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