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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/800

Title: Novel self-assembled decavanadate clusters forming 1D molecular chains and 2D molecular arrays: [HMTA-H···H2O][HMTA-CH2OH][H3V10O28{Na(H2O)4}]·4H2O and [Na2(H2O)10] [H3V10O28 {Na(H2O)2}]·3H2O
Authors: Duraisamy, T
Ramanan, A
Vittal, J J
Keywords: Polyoxovanadates
Decavanadates
Crystal structure
Issue Date: 2000
Citation: Crystal Engineering, 3(4), 237–250
Abstract: Two novel materials, [HMTA-H··H2O] [HMTA-CH2OH] [H3V10O28[Na(H2O)4}]·4H2O, 1 and [Na2(H2O)10][H3V10O28[Na(H2O)2}]·3H2O, 2 containing decavanadate clusters interconnected through hydrated sodium cations forming 1D molecular chains and 2D molecular arrays have been self-assembled from acidified, aqueous vanadate solution in the presence of organic bases, hexamethylenetetramine and 1,3,5-triazine respectively.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/800
Appears in Collections:Chemistry

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