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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/870

Title: Hydrothermal synthesis of new organically intercalated layered vanadates
Authors: Sharma, S
Ramanan, A
Jansen, M
Keywords: Hydrothermal synthesis
Vanadium oxide
Patterson plots
Issue Date: 2004
Citation: Solid State Ionics, 170(1-2), 93–98
Abstract: In the present work we report the synthesis of four organic cation intercalated layered vanadium oxide bronzes by mild hydrothermal reactions: [(C6H5)4As]0.19 + V2O5, c-17.7 A ; [(C6H5)4P]0.20 + V2O5, c-17.2 A ; [(C4H9)4P]0.19 + V2O5, c-16.3A and [(C2H5)4N]0.58 + V2O5, c-12.7 A . The layered solids were characterized using X-ray powder diffraction, electron microcopy, thermal analysis, FTIR and X-ray emission analysis. All the solids exhibited layered characteristics analogous to vanadium oxide xerogel. One-dimensional Patterson plots and electron density calculations suggest vanadium oxide bi-layer structure with organic molecules occupying inter-lamellar region.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/870
Appears in Collections:Chemistry

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