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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/927

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dc.contributor.authorSharma, S-
dc.contributor.authorRamanan, A-
dc.contributor.authorJansen, M-
dc.date.accessioned2005-10-18T05:33:00Z-
dc.date.available2005-10-18T05:33:00Z-
dc.date.issued2004-
dc.identifier.citationSolid State Ionics, 170(1-2), 93–98en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/927-
dc.description.abstractIn the present work we report the synthesis of four organic cation intercalated layered vanadium oxide bronzes by mild hydrothermal reactions: [(C6H5)4As]0.19+V2O5, c17.7 Å; [(C6H5)4P]0.20+V2O5, c17.2 Å; [(C4H9)4P]0.19+V2O5, c16.3Å and [(C2H5)4N]0.58+V2O5, c12.7 Å. The layered solids were characterized using X-ray powder diffraction, electron microcopy, thermal analysis, FTIR and X-ray emission analysis. All the solids exhibited layered characteristics analogous to vanadium oxide xerogel. One-dimensional Patterson plots and electron density calculations suggest vanadium oxide bi-layer structure with organic molecules occupying inter-lamellar region.en
dc.format.extent1286541 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectHydrothermal synthesisen
dc.subjectVanadium oxideen
dc.subjectPatterson plotsen
dc.titleHydrothermal synthesis of new organically intercalated layered vanadatesen
dc.typeArticleen
Appears in Collections:Chemistry

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