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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/928

Title: Structure-directing role of hydrogen-bonded dimers of phenylenediammonium cations: supramolecular assemblies of octamolybdate-based organic-inorganic hybrids
Authors: Upreti, Shailesh
Ramanan, Arunachalam
Keywords: crystallization
hybrid solids
octamolybdate
structure-directing
hydrogen-bonded organic dimers
multidimensional networks
phenylenediammonium
octamolybdate anions
Issue Date: 2005
Citation: Crystal Growth & Design, 5(5), 1837-1843
Abstract: Crystallization of three new organic/inorganic hybrid solids (1-3) based on octamolybdate under selfassembly conditions has demonstrated the structure-directing role of three hydrogen-bonded organic dimers (supramolecular synthons) in the construction of multidimensional networks. In acidified aqueous molybdate solution, isomeric phenylenediammonium ions form dimers through strong hydrogen-bonding and/or π-π interactions, which in turn dictate the supramolecular assemblies between themselves or with octamolybdate anions that eventually result in the growth of hybrid solids.
URI: http://eprint.iitd.ac.in/dspace/handle/2074/928
Appears in Collections:Chemistry

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