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Please use this identifier to cite or link to this item: http://hdl.handle.net/2074/928

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contributor.authorUpreti, Shailesh-
contributor.authorRamanan, Arunachalam-
date.accessioned2005-10-18T05:33:13Z-
date.available2005-10-18T05:33:13Z-
date.issued2005-
identifier.citationCrystal Growth & Design, 5(5), 1837-1843en
identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/928-
description.abstractCrystallization of three new organic/inorganic hybrid solids (1-3) based on octamolybdate under selfassembly conditions has demonstrated the structure-directing role of three hydrogen-bonded organic dimers (supramolecular synthons) in the construction of multidimensional networks. In acidified aqueous molybdate solution, isomeric phenylenediammonium ions form dimers through strong hydrogen-bonding and/or π-π interactions, which in turn dictate the supramolecular assemblies between themselves or with octamolybdate anions that eventually result in the growth of hybrid solids.en
format.extent1733615 bytes-
format.mimetypeapplication/pdf-
language.isoenen
subjectcrystallizationen
subjecthybrid solidsen
subjectoctamolybdateen
subjectstructure-directingen
subjecthydrogen-bonded organic dimersen
subjectmultidimensional networksen
subjectphenylenediammoniumen
subjectoctamolybdate anionsen
titleStructure-directing role of hydrogen-bonded dimers of phenylenediammonium cations: supramolecular assemblies of octamolybdate-based organic-inorganic hybridsen
typeArticleen
Appears in Collections:Chemistry

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