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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/970

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dc.contributor.authorSingh, Ajai K-
dc.contributor.authorSooriyakumar, J-
dc.contributor.authorDrake, J E-
dc.contributor.authorHursthouse, M B-
dc.contributor.authorLight, M E-
dc.date.accessioned2005-10-20T04:24:58Z-
dc.date.available2005-10-20T04:24:58Z-
dc.date.issued2000-
dc.identifier.citationJournal of Organometallic Chemistry, 613(2), 244–249en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/970-
dc.description.abstractSodium telluride (Na2Te), obtained in situ by borohydride reduction of elemental tellurium, reacts with 2-(2-bromoethyl)-1,3- dioxane resulting in bis(2-{1,3-dioxan-2-yl}ethyl) telluride (L), which is isolated as an unstable viscous liquid. The potentially (Te,O2) type of ligand L is stabilized on the formation of complexes [Ru(p-cymene)Cl2L] (1) and trans-[PdCl2(L)2] (2) which are characterized structurally. The Ru–Te bond length in the half sandwich compound 1 is 2.6559(9) A, . The geometry of Pd in 2 is square planar. The Pd–Te bond length in 2 is 2.5873(2) A, . 1 and 2 are the first examples of structurally characterized complexes in which potentially (Te,O2) type ligand molecules are present, of course coordinating through Te only.en
dc.format.extent220582 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectBis(2-{1,3-dioxan-2-yl}ethyl) tellurideen
dc.subjectPalladiumen
dc.subjectRutheniumen
dc.subjectComplexationen
dc.subjectCrystal structureen
dc.titleBis(2-{1,3-dioxan-2-yl}ethyl) telluride (L): synthesis and ligation with Pd(II) and Ru(II). Crystal structures of [Ru(p-cymene)Cl2L] and trans-[PdCl2(L)2]en
dc.typeArticleen
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