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Please use this identifier to cite or link to this item: http://hdl.handle.net/2074/982

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DC Field	Value	Language
contributor.author	Ayyappan, P	-
contributor.author	Ramanan, A	-
date.accessioned	2005-12-20T06:08:32Z	-
date.available	2005-12-20T06:08:32Z	-
date.issued	1998	-
identifier.citation	Inorganic Chemistry, 37(14), 3629	en
identifier.uri	http://eprint.iitd.ac.in/dspace/handle/2074/982	-
description.abstract	Three new, mixed-valent layered vanadyl phosphates, Ag0.43VOPO4‚2H2O (AgVPO), Cu0.16VOPO4‚2.5H2O (CuVPO), and Zn0.11VOPO4‚2.5H2O (ZnVPO), have been synthesized hydrothermally and their structures determined by single-crystal X-ray diffraction: AgVPO is triclinic, space group P1h, a ) 6.287(1), b ) 6.283(1),and c ) 13.240(1) Å, R ) 80.98(1), ‚ ) 86.58(1) and Á ) 90.00(1)°, Z ) 4; CuVPO is triclinic, space group P1h, a ) 6.260(2), b ) 6.249(3), and c ) 7.257(1) Å, R ) 83.62(3), ‚ ) 73.99(2), and Á ) 90.13(4)°, Z ) 2; ZnVPO is triclinic, space group P1h, a ) 6.252(1), b ) 6.248(2), and c ) 7.339(3) Å, R ) 83.24(4), ‚ ) 73.93(2), and Á ) 90.00(2)°, Z ) 2. The structures are related to that of VOPO4‚2H2O. Metal powders have been found to be effective both as reductants and as countercations.	en
format.extent	559782 bytes	-
format.mimetype	application/pdf	-
language.iso	en	en
subject	mixed-valent layered	en
subject	vanadyl phosphates	en
subject	synthesized hydrothermally	en
subject	single-crystal X-ray diffraction	en
subject	as reductants	en
subject	as countercations	en
title	New metal-intercalated layered vanadyl phosphates, MxVOPO4‚yH2O (M ) Ag, Cu, Zn)	en
type	Article	en
Appears in Collections:	Chemistry

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