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Please use this identifier to cite or link to this item: http://eprint.iitd.ac.in/handle/2074/982

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dc.contributor.authorAyyappan, P-
dc.contributor.authorRamanan, A-
dc.date.accessioned2005-12-20T06:08:32Z-
dc.date.available2005-12-20T06:08:32Z-
dc.date.issued1998-
dc.identifier.citationInorganic Chemistry, 37(14), 3629en
dc.identifier.urihttp://eprint.iitd.ac.in/dspace/handle/2074/982-
dc.description.abstractThree new, mixed-valent layered vanadyl phosphates, Ag0.43VOPO4‚2H2O (AgVPO), Cu0.16VOPO4‚2.5H2O (CuVPO), and Zn0.11VOPO4‚2.5H2O (ZnVPO), have been synthesized hydrothermally and their structures determined by single-crystal X-ray diffraction: AgVPO is triclinic, space group P1h, a ) 6.287(1), b ) 6.283(1),and c ) 13.240(1) Å, R ) 80.98(1), ‚ ) 86.58(1) and Á ) 90.00(1)°, Z ) 4; CuVPO is triclinic, space group P1h, a ) 6.260(2), b ) 6.249(3), and c ) 7.257(1) Å, R ) 83.62(3), ‚ ) 73.99(2), and Á ) 90.13(4)°, Z ) 2; ZnVPO is triclinic, space group P1h, a ) 6.252(1), b ) 6.248(2), and c ) 7.339(3) Å, R ) 83.24(4), ‚ ) 73.93(2), and Á ) 90.00(2)°, Z ) 2. The structures are related to that of VOPO4‚2H2O. Metal powders have been found to be effective both as reductants and as countercations.en
dc.format.extent559782 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoenen
dc.subjectmixed-valent layereden
dc.subjectvanadyl phosphatesen
dc.subjectsynthesized hydrothermallyen
dc.subjectsingle-crystal X-ray diffractionen
dc.subjectas reductantsen
dc.subjectas countercationsen
dc.titleNew metal-intercalated layered vanadyl phosphates, MxVOPO4‚yH2O (M ) Ag, Cu, Zn)en
dc.typeArticleen
Appears in Collections:Chemistry

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