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Nanocrystallite formation in Pd capped PrH3_2δ films

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Author: Mor, G K; Malhotra, L K

Advisor: Advisor

Date: 2003

Publisher:
Citation: Solid Stat

Series/Report no.:
Item Type: Article

Keywords: Nanostructure; Praseodymium hydride; Palladium; Optical properties

Abstract: Restricting the palladium cap layer thickness to ≤9 nm on top of 170 nm Pr films during in situ hydrogen loading has been shown to result in nanocrystallite size PrH32dfilms even though the deposited Pr films are of large crystallite size. The effect is attributed to hydrogen-induced stresses in the PrH32dfilms, which trigger structural rearrangement. These nanocrystalline films show a blue shift of the transmittance edge with respect to PrH32d films of large crystallite size. The approximate size of the nanocrystallites calculated from the blue shift using an effective mass approximation (EMA) theory is supported by XRD, TEM and AFM measurements.
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Shankar B. Chavan
Computer Applications Division
Central Library, IIT Delhi
shankar.chavan@library.iitd.ac.in
NDLTD
Shodhganga
NDL
ePrints@IISc
etd@IISc
IR@IIT Bombay
NewsClips @IITD
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