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Novel topotactic conversion of an organically templated vanadyl phosphate framework into layered structures
Asnani, Minakshi; Sharma, Sanjeev; Lofland, Samuel E; Ramanujachary, Kandalam V; Buffat, Philippe A; Ramanan, Arunachalam (2005)This paper reports a novel topotactic exchange reaction of the ethylenediammonium intercalated mixed-valent vanadyl phosphate, (H3NCH2CH2NH3)0.5[V4+ 0.45V5+ 0.55O2PO4- {P(OH)2}0.483], with monovalent cations at room ... -
New metal-intercalated layered vanadyl phosphates, MxVOPO4‚yH2O (M ) Ag, Cu, Zn)
Ayyappan, P; Ramanan, A (1998)Three new, mixed-valent layered vanadyl phosphates, Ag0.43VOPO4‚2H2O (AgVPO), Cu0.16VOPO4‚2.5H2O (CuVPO), and Zn0.11VOPO4‚2.5H2O (ZnVPO), have been synthesized hydrothermally and their structures determined by single-crystal ...