Author: | Batheja, Raman; Dhingra, S K; Singh, Ajai K |
Advisor: | Advisor |
Date: | 1995
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Publisher: | |
Citation: | Journal of
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Series/Report no.: |
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Item Type: | Article
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Keywords: | Palladium; Tellurium; Sulfur |
Abstract: | Five ternary complexes of palladium(II) namely [Pd(L1)2](C104)2 (1), [Pd(LIXL2)](C104)2 (2), [(PPh3)2Pd(LI)](C104)2 (3), [(DPPE)Pd(L2)](C104)2 (4) and [Pd(L1XL3)](C104)2 (5) where L 1 =
MeSCH2CH2TeAr , L 2 = Me2NCH2CHzTeAr (At = 4-MeOC6H 4) and L 3 = MeSCH2CH(OH)CHzSMe were synthesized by treating [PdC12l1 (El)] or [(PPh3)z/(DPPE)PdCI2)] with AgC10 4 and the
appropriate ligand. The ligands L a, L z and L 3 in these complexes are judged to be coordinated in bidentate mode on the basis of 1H NMR
and IR spectral data. All the complexes behave as 1 : 2 electrolytes in CH3CN. The 125Te{1H} NMR spectra of 1 and 2 indicate that the
ligands L 1 and L z in them are in a cis disposition in freshly prepared dimethylsulphoxide-d6-CD3CN solutions, implying a similar configuration in the solid state but within a few hours there is partial conversion into the trans isomer. |