Browsing Faculty Research Publications by Author "Kadarkaraisamy, M"
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2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L2): synthesis, reactions of L1 with iodine and ligation of L1 with Ru(II), Cu(I), and Hg(II) and L2 with Ru(II). Crystal structures of [RuCl2(p-cymene)·L1/L2]
Singh, Ajai K; Kadarkaraisamy, M; Mishra, M; Sooriyakumar, J; Drake, J E; Hursthouse, M B; Light, M E; Jasinski, Jerry P (2001)2-(4-Ethoxyphenlytelluromethyl)tetrahydro-2H-pyran (L1) and 2-(2-{4-ethoxyphenyl}telluroethyl)-1,3-dioxane (L2) have been synthesized by reacting in situ generated ArTe−Na+ with an appropriate organic halide. The reaction ... -
Ditelluroether ligand bis(4-methoxyphenyltelluro)methane — synthesis, reaction with iodine and its ruthenium(II) complexes. Crystal structures of (4-MeOC6H4Te)2CH2, {4-MeO-C6H4Te(I2)}2CH2 cis-[Ru(DMSO)2Cl2(4-MeOC6H4Te)2CH2] and [(p-cymene)Cl2Ru(m-{(4-MeOC6H4Te)2CH2})RuCl2(p-cymene)]
Singh, Ajai K; Kadarkaraisamy, M; Drake, J E; Butcher, R J (2000)The reaction of chloroform with ArTe- Na+ (Ar=4-MeOC6H4), generated in situ by borohydride reduction of Ar2Te2, results in a high purity sample of bis(4- ethoxyphenyltelluro)methane (1) (yield -90%). Its single crystal ... -
N-[2-(4-Methoxyphenyltelluro)ethyl]benzamide (L1) and N-[2-(4-methoxyphenyl telluro)propyl] phthalimide (L2): synthesis and ligation with palladium(II), platinum(II) and ruthenium(II). Crystal structures of L1 and L2, the latter as a mixed crystal with L2H2
Singh, Ajai K; Sooriyakumar, J; Kadarkaraisamy, M; Drake, John E; Hursthouse, Michael B; Light, Mark E; Butcher, Raymond J (2002)The reactions of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe− Na+ generated in situ by borohydride reduction of Ar2Te2, have resulted in N-[2-(4-methoxyphenyltelluro)ethyl]benzamide (L1) and ... -
N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (L1): synthesis, oxidation by ruthenium(III) chloride and ligation with ruthenium(II). Crystal structures of L1, its oxidized product and of [RuCl2(p-cymene)·L1]
Singh, Ajai K; Kadarkaraisamy, M; Murthy, G S; Srinivas, J; Varghese, B; Butcher, R J (2000)N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (L1) synthesized by reacting ArTe- (generated in situ) with N-(2-bromoethyl)phthalimide, has been characterized structurally. The Te-C(alkyl) (2.147(5) A, ) is somewhat longer ...