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u-Oxobridged heterotrinuclear compounds containing antimony(V) and arsenic(III). Crystal structures of Ar3Sb(u-OAsPh2)2 (Ar=Ph or p-tol)
(1999)
Novel compounds containing open chain Sb(OAs)2 units have been synthesised by reacting Ar3SbBr2 (Ar-Ph or p-tol) with
Ph2AsLi in dry THF:benzene under a N2 atmosphere, followed by a work up of the reaction mixture under ...
2-(2-{Diphenylarsino}ethyl)-1,3-dioxane (L1) and 2-(diphenylarsinomethyl)tetrahydrofuran (L2) and their palladium(II), platinum(II) and mercury(II) complexes: synthesis and crystal structures of [PdBr2(L1)2] and [HgBr2(L2)]2
(1999)
Novel and potentially hemilabile ligands of (As, O) type, 2-(2-{diphenylarsino}ethyl)-1,3-dioxane (L1) and 2- diphenylarsinomethyl)tetrahydrofuran (L2), are synthesised by reacting Ph2AsLi generated in situ under a nitrogen ...
First example of bimetallic complex of platinum(II) with a hybrid organotellurium ligand [(4-MeOC6H4Te)CH2CH2OCH2CH2CH2(2-C5H4N)] (L1) containing 20-membered metallomacrocycle ring: synthesis and crystal structure
(2003)
1-(4-Methoxyphenyltelluro)-2-[3-(6 methyl-2 pyridyl)propoxy]ethane (L1) and its complexes [MCl2(L1)]2 (M = Pd or Pt) have been synthesized. The single crystal X-ray diffraction of [PtCl2(L1)]2 · 2CHCl3 shows a bimetallic ...
Bis(2-{1,3-dioxan-2-yl}ethyl) telluride (L): synthesis and ligation with Pd(II) and Ru(II). Crystal structures of [Ru(p-cymene)Cl2L] and trans-[PdCl2(L)2]
(2000)
Sodium telluride (Na2Te), obtained in situ by borohydride reduction of elemental tellurium, reacts with 2-(2-bromoethyl)-1,3-
dioxane resulting in bis(2-{1,3-dioxan-2-yl}ethyl) telluride (L), which is isolated as an unstable ...
2-[2-(4-Methoxyphenyltelluro)ethyl]thiophene (L1) bis[2-(2-thienyl)ethyl] telluride (L2) and their metal complexes; crystal structure of trans-dichlorobis{2-(2-(4-methoxyphenyltelluro)ethyl)thiophene-Te} palladium(II) and {bis[2-(2-thienyl)ethyl] telluride}dichloro(p-cymene)ruthenium(II)
(2004)
The reaction of ArTe− (Ar=4-MeOC6H4) and Te2− generated in situ by borohydride reduction of Ar2Te2 and Te, respectively, with 2-(2-thienyl)ethyl chloride has resulted in 2-[2-(4-methoxyphenyltelluro)ethyl]thiophene (L1) ...
N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (L1): synthesis, oxidation by ruthenium(III) chloride and ligation with ruthenium(II). Crystal structures of L1, its oxidized product and of [RuCl2(p-cymene)·L1]
(2000)
N-[2-(4-methoxyphenyltelluro)ethyl]phthalimide (L1) synthesized by reacting ArTe- (generated in situ) with N-(2-bromoethyl)phthalimide, has been characterized structurally. The Te-C(alkyl) (2.147(5) A, ) is somewhat longer ...
Hybrid (Te, N) and (N, Te, N) ligands having pyrrolidine ring and their palladium(II) and mercury(II) complexes: synthesis and crystal structures
(2003)
Reactions of (2-choroethyl)pyrrolidine hydrochloride with ArTe− or Te2− generated in situ by borohydride reduction of Ar2Te2 or elemental tellurium give N-{2-(4-methoxyphenyltelluro)ethyl}pyrrolidine (L1) or bis{2-(pyrro ...